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曾晓飞

来源 : 澳门合法搏彩网     编辑 : 澳门合法搏彩网     时间 : 2017-10-21     点击次数 : 4258

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        曾晓飞,男,教授,硕士研究生导师,浙江省高校中青年学科带头人。1983年5月生,江西吉安人。2003年本科毕业于南昌大学,2006年硕士毕业于苏州大学,2010 年博士毕业于新加坡南洋理工大学化学与生物化学系,师从著名有机化学家钟国富教授(长江学者、南洋理工大学化学与生物化学系创系教授之一),主要从事新型手性催化剂的设计、合成及不对称催化反应研究、药物合成研究。2011-2012年作为高级研究员就职于美国Albany新药研发企业新加坡分企业。同年获得德国洪堡学者奖学金并于2012年2月-2013年7月在德国亚琛工业大学有机化学研究所从事博士后研究工作,合作教授为世界著名有机化学家Dieter Enders教授。2013年11月起以特聘教授入职澳门网上网站大全娱乐至今,2016年12月晋升为教授。2014年获得德国Thieme杂志社颁发的Thieme Chemistry Journal Award;同年获得杭州市“西湖学者”称号;2017年被评为杭州市教育局系统优秀教师;是浙江省高校中青年学科带头人,杭州市“创新药物研究”重中之重实验室分方向负责人。主持了包括国家自然科学基金、浙江省自然科学基金、浙江省公益技术应用研究计划项目、杭州市留学回国人员创业创新项目等项目。近年来,引导本科学生获得省级竞赛奖项4次、“国创”项目2项、新苗计划1项、省级优秀毕业论文1人,校级本创项目3项,恒逸星光奖2项。在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Org. Lett.、Chem. Commun.等国际一流杂志上发表SCI论文40余篇,被他引1300余次。现为Angew. Chem. Int. Ed.、Chem. Commun.、J. Org. Chem.、Org. Biomol. Chem.、Curr. Org. Chem.等杂志特约审稿人。

电话:15157124399;邮箱:chemzxf@hznu.edu.cn; chemzxf@163.com

教育与学术经历:
1999.09-2003.07           南昌大学化学与材料科学学院 获学士 (B. Eng)学位
2003.09-2006.07           苏州大学化学化工学院 获硕士 (M.Eng)学位
2006.08-2010.07           新加坡南洋理工大学化学系 获理学博士 (Ph.D.)学位
2010.08-2011.01           新加坡南洋理工大学化学系 研究助理
2011.02-2012.01           美国Albany制药新加坡企业 高级研究员
2012.02-2013.07           德国亚琛工业大学有机化学研究所 博士后(洪堡学者)
2013.10-至今             澳门合法搏彩网 教授

科研项目


1111



荣誉和奖励:
2006 江苏省优秀硕士毕业论文
2011 AvH Humboldt Scholarship (洪堡学者奖学金)
2014 Thieme Chemistry Journal Award
2014 杭州市“西湖学者”
2017 杭州市教育局系统优秀教师
2017 浙江省高校中青年学科带头人

发表论文:(第一编辑或通讯编辑论文)
1.Pan, S.-L.; Wu, B.-Q.; Hu, J.-J.; Xu, R.-G.; Jiang, M.; Zeng, X.-F.; Zhong, G. Palladium-Catalyzed Allylic Substitution Reaction of Benzothiazolylacetamide with Allylic Alcohols in Water, J. Org. Chem. 2019, 84, Just accepted.
2.Hou, Y.-X., Hu, J.-J.; Xu, R.-G.; Pan, S.-L.; Zeng, X.-F.; Zhong, G. Indium-Mediated Synthesis of Benzylic Hydroperoxides, Org. Lett. 2019, 21, 4428?4432.
3.Yan, P.-P., Pan, S.-L.; Hu, J.-J.; Lu, L.-M.; Zeng, X.-F.; Zhong, G. Palladium Catalyzed Controllable Mono- or Di-Allylic Substitution Reaction of Benzothiazolylacetate with Allylic Alcohols, Adv. Synth. Catal. 2019, 361, 1322-1334.
4.Yang, P.-F.; Xu, W.-Y.; Wang, R.-C.; Zhang, M.; Xie, C.-S.; Zeng, X.-F.; Wang, M. Potassium tert-Butoxide-Mediated Condensation Cascade Reaction: Transition Metal-Free Synthesis of Multisubstituted Aryl Indoles and Benzofurans, Org. Lett. 2019, 21, 3658?3662.
5.Zhang, L.-Y.; Wu, B.-Q.; Chen, Z.-T.; Hu, J.-J.; Zeng, X.-F.; Zhong, G. Chiral phosphoric acid catalyzed enantioselective N-alkylation of indoles with in situ generated cyclic N-acyl ketimines Chem. Commun. 2018, 54, 9230-9233.
6.章吕烨,吴彬强,陈张涛,胡锦锦,曾晓飞,钟国富,三氟甲磺酸催化的2,3'-二吲哚衍生物的合成,Chin. J. Org. Chem. 2018, 38, 2028-2035。
7.TiCl4/DMAP mediated Z-selective knovenagel condensation of isatins with nitroacetates and related compounds, Zhu L.-Y.; Yan, P.-P.; Zhang, L.-Y.; Chen, Z.-T. Zeng, X.-F.; Zhong, G. RSC Adv. 2017, 7(81), 51352-51358.
8.Construction of tetrahydropyranoquinoline derivatives via an asymmetric organocatalytic aza-Michael-IED/HAD cascade reaction, Dai, L.; Hou, Y.-X.; Zhang, L.-Y.; Chen, Z.-T.; Zeng, X.-F.; Zhong, G. Org. Biomol. Chem. 2017, 15(45), 9630-9637.
9.Synthesis of Cyano-Containing Phenanthridine Derivatives via Catalyst-, Base-, and Oxidant-Free Direct Cyanoalkylarylation of Isocyanides Song, W.-H.; Yan, P.-P.; Shen, D.; Chen, Z.-T.; Zeng, X.-F.; Zhong, G. J. Org. Chem. 2017, 82(8), 4444-4448.
10.A highly enantioselective Friedel-Crafts reaction of 3,5-dimethoxylphenol with nitroolefins mediated by a bifunctional quinine derived thiourea catalyst Han, X.-Y.; Ye. C.; Chen. F.-F.; Chen, Q.; Wang, Y.-J.; Zeng, X.-F. Org. Biomol. Chem. 2017, 15(16), 3401-3407.
11.Enantioselective Dearomatization of Naphthol Derivatives with Allylic Alcohols by Cooperative Iridium and Bronsted Acid Catalysis Shen, D.; Chen, Q.-L.; Yan, P.-P.; Zeng, X.-F.; Zhong, G. Angew. Chem. Int. Ed. 2017, 56(12), 3242-3246.
12.N-Heterocyclic Carbene/Lewis Acid Catalyzed Enantioselective Aerobic Annulation of α,β-Unsaturated Aldehydes with 1,3-Dicarbonyl Compounds Xie. D.-B.; Shen, D.; Chen, Q.-L.; Zhou, J.-Q.; Zeng, X.-F.; Zhong, G. J. Org. Chem. 2016, 81(14), 6136-6141.
13.Enantioselective Construction of Spirocyclic Oxindole Derivatives with Multiple Stereocenters via an Organocatalytic Michael/Aldol/Hemiacetalization Cascade Reaction Zhu, L.-Y.; Chen, Q.-L.; Shen, D.; Zhang, W.-H.; Shen, C.; Zeng, X.-F.; Zhong, G. Org. Lett. 2016, 18(10), 2387.2390.
14.Assembly of Enantioenriched cis-3a,8a-Hexahydropyrrolo[2,3-b]indole Scaffolds by Silver(I)-Catalyzed Asymmetric Domino Reaction of Isocyanoacetates in the Presence of Cinchona-Derived Chiral Phosphorus Ligands Cheng, H.-G.; Zhang, R.-M.; Yang, S.-W.; Wang, M.; Zeng, X.-F.; Xie, L.-J.; Xie, C.-S.; Wu, J. Zhong, G. Adv. Synth. Catal. 2016, 358(6), 970-976.
15.Highly Enantio- and Diastereoselective L-Proline Derived Acetylglucose Amide Catalyzed Aldol Reaction of Ketones to Aldehydes under Solvent-Free Conditions Han, X.-Y.; Wang, Y.-J.; Gai, X.-K.; Zeng, X.-F. Synlett 2015, 26(20), 2858-2862.
16.N-Heterocyclic Carbene-Catalyzed Activation of Esters of N-Hydroxyphthalimide: A Highly Enantioselective Route to Chiral Dihydropyridinones Bearing an All Carbon Quaternary Stereogenic Center Zhang, Z.-M.; Zeng, X.-F.; Xie, D.-B.; Chen, D.-D.; Ding, L.-Y.; Wang, A.-N.; Yang, L.-M.; Zhong, G. Org. Lett. 2015, 17(20), 5052-5055.
17.Synthesis of 3-Oxazolines via SnCl4-Promoted Formal [3+2] Cycloaddition of Donor-Acceptor Oxiranes and Nitriles Zhou, H.; Zeng, X.-F.; Xie, Y.; Zhong, G. Synlett 2015, 26(12), 1693-1696.
18.Triflic Acid Catalyzed Formal [3 + 2] Cycloaddition of Donor-Acceptor Oxiranes and Nitriles: A Facile Access to 3-Oxazolines Zhou, H.; Zeng, X.-F.; Ding, L.-Y.; Xie, Y.; Zhong, G. Org. Lett. 2015, 17(10), 2385-2387.
19.Rapid Access to Spirocylic Oxindoles: Application of Asymmetric N-Heterocyclic Carbene-Catalyzed [3 + 3] Cycloaddition of Imines to Oxindole-Derived Enals Xie, D.-B.; Yang, L.-M.; Lin, Y.-Q.; Zhang, Z.-M.; Chen, D.-D.; Zeng, X.-F.; Zhong, G. Org. Lett. 2015, 17(10), 2318-2321.
20.A Branched Domino Reaction: Asymmetric Organocatalytic Two-Component Four-Step Synthesis of Polyfunctionalized Cyclohexene Derivatives Zeng, X.-F.; Ni. Q.-J.; Raabe, G.; Enders, D. Angew. Chem. Int. Ed. 2013, 52(10), 2977-2980.
21.Chiral Bronsted Acid Catalyzed Enantioselective Addition of α-Isocyanoacetamides to Aldehydes Zeng, X.-F.; Ye. K.-H.; Lu, M.; Chua, P. J.; Tan, B.; Zhong, G. Org. Lett. 2010, 12(10), 2414-2417.
22.Highly Efficient Asymmetric Trans-Selective Aziridination of Diazoacetamides and N-Boc-imines Catalyzed by Chiral Bronsted Acids Zeng, X.-F.; Zeng, X.; Xu, Z.-J.; Lu, M.; Zhong, G. Org. Lett. 2009, 11(14), 3036-3039.
23.Prolinol sulfinyl ester derivatives: organocatalytic Michael addition of ketones to nitroolefins under neat conditions Zeng, X.-F.; Zhong, G. Synthesis 2009, 9, 1545-1550.
24.Facile synthesis of symmetrical triindolylmethanes catalyzed by iodine under solvent-free condition Zeng, X.-F.; Ji. S.-J.; Su. X.-M. Chin. J. Chem. 2008, 26(3), 413-416.
25.Conjugate addition of indoles to α,β-unsaturated ketones (chalcones) catalyzed by KHSO4 under ultrasonic conditions Zeng, X.-F.; Ji. S.-J.; Shen, S.-S.; Chin. J. Chem. 2007, 25(12), 1777-1780.
26.An efficient synthesis of bis(indolyl)methanes (BIAs) catalyzed by a recyclable solid superacid SO42-/TiO2 under solvent-free condition Zeng, X.-F.; Ji. S.-J. Lett. Org. Chem. 2006, 3(5), 374-378.
27.Novel method for synthesis of unsymmetrical bis(indolyl)alkanes catalyzed by ceric ammonium nitrate (CAN) under ultrasonic irradiation Zeng, X.-F.; Ji. S.-J.; Wang, S.-Y. Tetrahedron 2005, 61(43), 10235-10241.

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